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Beilstein J. Org. Chem. 2024, 20, 578–588, doi:10.3762/bjoc.20.50
Graphical Abstract
Figure 1: Examples of bioactive fungal meroterpenoids.
Figure 2: The diversity of DMOA-derived meroterpenoid biosyntheses.
Figure 3: The combinatorial biosynthesis of diterpene pyrone meroterpenoids. The production of subglutinol A ...
Figure 4: The biosynthetic reaction from the common intermediate 21 to ascochlorin (22) and ascofuranone (23)...
Figure 5: The multistep oxidations catalyzed by AusE and PrhA from the common intermediate 24.
Figure 6: Reactions of SptF with native substrates 31 and 32.
Figure 7: A) Reactions of SptF with unnatural substrates. B) Reactions of SptF variants with 31.
Figure 8: The reaction of the αKG enzyme AndA and its variants generated via saturated mutagenesis.
Figure 9: The synthetic biological production of daurichromenic acid and its halogenated derivative.
Beilstein J. Org. Chem. 2019, 15, 1545–1551, doi:10.3762/bjoc.15.157
Figure 1: The reactions of aromatic PTases.
Figure 2: The reactions catalyzed by AmbP1 (A) and AmbP3 (B).
Figure 3: The overall structure of apo-AmbP1 (A), the Mg2+-free structure (B), and the Mg2+-bound structure (...
Figure 4: The active site structure of AmbP1. 1 and GSPP were bound in the active site without Mg2+ (A, Mg2+-...
Figure 5: The active site structure of AmbP3 with substrates. The AmbP3 structure in complex with hapalindole...
Figure 6: Multiple amino acid sequence alignment of AmbP1, AmbP3, and other ABBA PTases, visualized by ESPrip...